Impact of subtle intermolecular interactions on the structure and dynamics of multicomponent supramolecular polymers

Publikationstyp:
Zeitschriftenaufsatz
Metadaten:
Autoren
  • Job NS Hanssen
  • Shikha Dhiman
Autoren-URL
https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:001088705400001&DestLinkType=FullRecord&DestApp=WOS_CPL
DOI
10.1039/d3cc04567f
eISSN
1364-548X
Externe Identifier
  • Clarivate Analytics Document Solution ID: W9HW1
  • PubMed Identifier: 37877229
ISSN
1359-7345
Ausgabe der Veröffentlichung
90
Zeitschrift
CHEMICAL COMMUNICATIONS
Paginierung
13466 - 13469
Datum der Veröffentlichung
2023
Status
Published
Titel
Impact of subtle intermolecular interactions on the structure and dynamics of multicomponent supramolecular polymers
Sub types
  • Article
Ausgabe der Zeitschrift
59

Datenquelle: Web of Science (Lite)

Andere Metadatenquellen:
Abstract
<jats:p>We propose a monomer-dopant approach to investigate how subtle variations in monomers, located away from the self-assembling core, influence the structural and dynamic behaviour of multicomponent supramolecular polymers.</jats:p>
Autoren
  • Job NS Hanssen
  • Shikha Dhiman
DOI
10.1039/d3cc04567f
eISSN
1364-548X
ISSN
1359-7345
Ausgabe der Veröffentlichung
90
Zeitschrift
Chemical Communications
Sprache
en
Online publication date
2023
Paginierung
13466 - 13469
Status
Published online
Herausgeber
Royal Society of Chemistry (RSC)
Herausgeber URL
http://dx.doi.org/10.1039/d3cc04567f
Datum der Datenerfassung
2024
Titel
Impact of subtle intermolecular interactions on the structure and dynamics of multicomponent supramolecular polymers
Ausgabe der Zeitschrift
59

Datenquelle: Crossref

Abstract
Multicomponent supramolecular polymers offer versatile dynamic and functional properties; however, the influence of the monomer chemical structures on their structure-dynamics-function relationship remains unclear. In this study, we investigated the subtle variations in monomer interactions using one monomer and its two dopant derivatives, with functionalization away from the self-assembling core. We systematically investigated their multicomponent supramolecular polymers using a combination of spectroscopy and super-resolution microscopy. Our results highlight the significant impact of the supplementary intermolecular interactions, resulting from the functional motifs located away from the core and present in small quantities, on the microstructure and dynamics. Thus, a comprehensive approach, combining spectroscopy, microscopy, and well-designed experiments, is essential for assessing multicomponent supramolecular polymers. These findings have implications for the rational design of functional multicomponent supramolecular materials.
Addresses
  • Department of Chemistry, Johannes Gutenberg University Mainz, Duesbergweg 10-14, D-55128, Mainz, Germany. shikha.dhiman@uni-mainz.de.
Autoren
  • Job NS Hanssen
  • Shikha Dhiman
DOI
10.1039/d3cc04567f
eISSN
1364-548X
Externe Identifier
  • PubMed Identifier: 37877229
Funding acknowledgements
  • Deutsche Forschungsgemeinschaft: 497845157
  • Johannes Gutenberg-Universität Mainz:
  • H2020 Marie Skłodowska-Curie Actions: 899987
Open access
false
ISSN
1359-7345
Ausgabe der Veröffentlichung
90
Zeitschrift
Chemical communications (Cambridge, England)
Sprache
eng
Medium
Electronic
Online publication date
2023
Paginierung
13466 - 13469
Datum der Veröffentlichung
2023
Status
Published
Datum der Datenerfassung
2023
Titel
Impact of subtle intermolecular interactions on the structure and dynamics of multicomponent supramolecular polymers.
Sub types
  • Journal Article
Ausgabe der Zeitschrift
59

Datenquelle: Europe PubMed Central

Abstract
Multicomponent supramolecular polymers offer versatile dynamic and functional properties; however, the influence of the monomer chemical structures on their structure-dynamics-function relationship remains unclear. In this study, we investigated the subtle variations in monomer interactions using one monomer and its two dopant derivatives, with functionalization away from the self-assembling core. We systematically investigated their multicomponent supramolecular polymers using a combination of spectroscopy and super-resolution microscopy. Our results highlight the significant impact of the supplementary intermolecular interactions, resulting from the functional motifs located away from the core and present in small quantities, on the microstructure and dynamics. Thus, a comprehensive approach, combining spectroscopy, microscopy, and well-designed experiments, is essential for assessing multicomponent supramolecular polymers. These findings have implications for the rational design of functional multicomponent supramolecular materials.
Autoren
  • Job NS Hanssen
  • Shikha Dhiman
Autoren-URL
https://www.ncbi.nlm.nih.gov/pubmed/37877229
DOI
10.1039/d3cc04567f
eISSN
1364-548X
Ausgabe der Veröffentlichung
90
Zeitschrift
Chem Commun (Camb)
Sprache
eng
Country
England
Paginierung
13466 - 13469
Datum der Veröffentlichung
2023
Status
Published online
Titel
Impact of subtle intermolecular interactions on the structure and dynamics of multicomponent supramolecular polymers.
Sub types
  • Journal Article
Ausgabe der Zeitschrift
59

Datenquelle: PubMed

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