Correlation of high-field and zero- to ultralow-field NMR properties using 2D spectroscopy
- Publikationstyp:
- Zeitschriftenaufsatz
- Metadaten:
-
- Autoren
- Ivan V Zhukov
- Alexey S Kiryutin
- Alexandra V Yurkovskaya
- John W Blanchard
- Dmitry Budker
- Konstantin L Ivanov
- Autoren-URL
- https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:000639911900001&DestLinkType=FullRecord&DestApp=WOS_CPL
- DOI
- 10.1063/5.0039294
- eISSN
- 1089-7690
- Externe Identifier
- Clarivate Analytics Document Solution ID: RM8MT
- PubMed Identifier: 33858171
- ISSN
- 0021-9606
- Ausgabe der Veröffentlichung
- 14
- Zeitschrift
- JOURNAL OF CHEMICAL PHYSICS
- Artikelnummer
- ARTN 144201
- Datum der Veröffentlichung
- 2021
- Status
- Published
- Titel
- Correlation of high-field and zero- to ultralow-field NMR properties using 2D spectroscopy
- Sub types
- Article
- Ausgabe der Zeitschrift
- 154
Datenquelle: Web of Science (Lite)
- Andere Metadatenquellen:
-
- Abstract
- <jats:p>The field of zero- to ultralow-field (ZULF) nuclear magnetic resonance (NMR) is currently experiencing rapid growth, owing to progress in optical magnetometry and attractive features of ZULF-NMR such as low hardware cost and excellent spectral resolution achieved under ZULF conditions. In this work, an approach is proposed and demonstrated for simultaneous acquisition of ZULF-NMR spectra of individual 13C-containing isotopomers of chemical compounds in a complex mixture. The method makes use of fast field cycling such that the spin evolution takes place under ZULF conditions, whereas signal detection is performed in a high-field NMR spectrometer. This method has excellent sensitivity, also allowing easy assignment of ZULF-NMR spectra to specific analytes in the mixture. We demonstrate that the spectral information is the same as that given by ZULF-NMR, which makes the method suitable for creating a library of ZULF-NMR spectra of various compounds and their isotopomers. The results of the field-cycling experiments can be presented in a convenient way as 2D-NMR spectra with the direct dimension giving the high-field 13C-NMR spectrum (carrying the chemical-shift information) and the indirect dimension giving the ZULF-NMR spectrum (containing information about proton–carbon J-couplings). Hence, the method can be seen as a variant of heteronuclear J-resolved spectroscopy, one of the first 2D-NMR techniques.</jats:p>
- Autoren
- Ivan V Zhukov
- Alexey S Kiryutin
- Alexandra V Yurkovskaya
- John W Blanchard
- Dmitry Budker
- Konstantin L Ivanov
- DOI
- 10.1063/5.0039294
- eISSN
- 1089-7690
- ISSN
- 0021-9606
- Ausgabe der Veröffentlichung
- 14
- Zeitschrift
- The Journal of Chemical Physics
- Sprache
- en
- Online publication date
- 2021
- Datum der Veröffentlichung
- 2021
- Status
- Published
- Herausgeber
- AIP Publishing
- Herausgeber URL
- http://dx.doi.org/10.1063/5.0039294
- Datum der Datenerfassung
- 2023
- Titel
- Correlation of high-field and zero- to ultralow-field NMR properties using 2D spectroscopy
- Ausgabe der Zeitschrift
- 154
Datenquelle: Crossref
- Abstract
- The field of zero- to ultralow-field (ZULF) nuclear magnetic resonance (NMR) is currently experiencing rapid growth, owing to progress in optical magnetometry and attractive features of ZULF-NMR such as low hardware cost and excellent spectral resolution achieved under ZULF conditions. In this work, an approach is proposed and demonstrated for simultaneous acquisition of ZULF-NMR spectra of individual <sup>13</sup>C-containing isotopomers of chemical compounds in a complex mixture. The method makes use of fast field cycling such that the spin evolution takes place under ZULF conditions, whereas signal detection is performed in a high-field NMR spectrometer. This method has excellent sensitivity, also allowing easy assignment of ZULF-NMR spectra to specific analytes in the mixture. We demonstrate that the spectral information is the same as that given by ZULF-NMR, which makes the method suitable for creating a library of ZULF-NMR spectra of various compounds and their isotopomers. The results of the field-cycling experiments can be presented in a convenient way as 2D-NMR spectra with the direct dimension giving the high-field <sup>13</sup>C-NMR spectrum (carrying the chemical-shift information) and the indirect dimension giving the ZULF-NMR spectrum (containing information about proton-carbon J-couplings). Hence, the method can be seen as a variant of heteronuclear J-resolved spectroscopy, one of the first 2D-NMR techniques.
- Addresses
- International Tomography Center, Novosibirsk 630090, Russia.
- Autoren
- Ivan V Zhukov
- Alexey S Kiryutin
- Alexandra V Yurkovskaya
- John W Blanchard
- Dmitry Budker
- Konstantin L Ivanov
- DOI
- 10.1063/5.0039294
- eISSN
- 1089-7690
- Externe Identifier
- PubMed Identifier: 33858171
- Funding acknowledgements
- Ministry of Science and Higher Education of the Russian Federation: 075-15-2020-779
- Marie Sklodowska-Curie Grant: 766402
- Open access
- false
- ISSN
- 0021-9606
- Ausgabe der Veröffentlichung
- 14
- Zeitschrift
- The Journal of chemical physics
- Sprache
- eng
- Medium
- Paginierung
- 144201
- Datum der Veröffentlichung
- 2021
- Status
- Published
- Datum der Datenerfassung
- 2021
- Titel
- Correlation of high-field and zero- to ultralow-field NMR properties using 2D spectroscopy.
- Sub types
- Journal Article
- Ausgabe der Zeitschrift
- 154
Datenquelle: Europe PubMed Central
- Abstract
- The field of zero- to ultralow-field (ZULF) nuclear magnetic resonance (NMR) is currently experiencing rapid growth, owing to progress in optical magnetometry and attractive features of ZULF-NMR such as low hardware cost and excellent spectral resolution achieved under ZULF conditions. In this work, an approach is proposed and demonstrated for simultaneous acquisition of ZULF-NMR spectra of individual 13C-containing isotopomers of chemical compounds in a complex mixture. The method makes use of fast field cycling such that the spin evolution takes place under ZULF conditions, whereas signal detection is performed in a high-field NMR spectrometer. This method has excellent sensitivity, also allowing easy assignment of ZULF-NMR spectra to specific analytes in the mixture. We demonstrate that the spectral information is the same as that given by ZULF-NMR, which makes the method suitable for creating a library of ZULF-NMR spectra of various compounds and their isotopomers. The results of the field-cycling experiments can be presented in a convenient way as 2D-NMR spectra with the direct dimension giving the high-field 13C-NMR spectrum (carrying the chemical-shift information) and the indirect dimension giving the ZULF-NMR spectrum (containing information about proton-carbon J-couplings). Hence, the method can be seen as a variant of heteronuclear J-resolved spectroscopy, one of the first 2D-NMR techniques.
- Autoren
- Ivan V Zhukov
- Alexey S Kiryutin
- Alexandra V Yurkovskaya
- John W Blanchard
- Dmitry Budker
- Konstantin L Ivanov
- Autoren-URL
- https://www.ncbi.nlm.nih.gov/pubmed/33858171
- DOI
- 10.1063/5.0039294
- eISSN
- 1089-7690
- Ausgabe der Veröffentlichung
- 14
- Zeitschrift
- J Chem Phys
- Sprache
- eng
- Country
- United States
- Paginierung
- 144201
- Datum der Veröffentlichung
- 2021
- Status
- Published
- Titel
- Correlation of high-field and zero- to ultralow-field NMR properties using 2D spectroscopy.
- Sub types
- Journal Article
- Ausgabe der Zeitschrift
- 154
Datenquelle: PubMed
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