The Synthesis of Dendritic EDOT-Peptide Conjugates and their Multistimuli-Responsive Self-Assembly into Supramolecular Nanorods and Fibers in Water

Publikationstyp:
Zeitschriftenaufsatz
Metadaten:
Autoren
  • Patrick Ahlers
  • Hendrik Frisch
  • Daniel Spitzer
  • Zuzana Vobecka
  • Filipe Vilela
  • Pol Besenius
Autoren-URL
https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:000342675900009&DestLinkType=FullRecord&DestApp=WOS_CPL
DOI
10.1002/asia.201402271
eISSN
1861-471X
Externe Identifier
  • Clarivate Analytics Document Solution ID: AQ3FS
  • PubMed Identifier: 24839177
ISSN
1861-4728
Ausgabe der Veröffentlichung
8
Zeitschrift
CHEMISTRY-AN ASIAN JOURNAL
Schlüsselwörter
  • nanostructures
  • pH switch
  • self-assembly
  • stimuli-responsive
  • supramolecular polymer
Paginierung
2052 - 2057
Datum der Veröffentlichung
2014
Status
Published
Titel
The Synthesis of Dendritic EDOT-Peptide Conjugates and their Multistimuli-Responsive Self-Assembly into Supramolecular Nanorods and Fibers in Water
Sub types
  • Article
Ausgabe der Zeitschrift
9

Datenquelle: Web of Science (Lite)

Andere Metadatenquellen:
Abstract
<jats:title>Abstract</jats:title><jats:p>We report the synthesis of amphiphilic dendritic EDOT–peptide conjugates and discuss their stimuli‐responsive self‐assembly into polyanionic nanorods in water. In order to expand the general concept of frustrated growth, whereby attractive supramolecular interactions within the enlarged π‐system of the hydrophobic core of a dendritic peptide are hampered by repulsive interactions in the hydrophilic periphery, we show that changes in the pH and ionic strength are both able to independently trigger the self‐assembly of the dendritic monomers into supramolecular nanorods and nanofibers. These transitions are analyzed using circular dichroism and fluorescence spectroscopic methods, and the resulting supramolecular polymers are characterized by transmission electron microscopy.</jats:p>
Autoren
  • Patrick Ahlers
  • Hendrik Frisch
  • Daniel Spitzer
  • Zuzana Vobecka
  • Filipe Vilela
  • Pol Besenius
DOI
10.1002/asia.201402271
eISSN
1861-471X
ISSN
1861-4728
Ausgabe der Veröffentlichung
8
Zeitschrift
Chemistry – An Asian Journal
Sprache
en
Online publication date
2014
Paginierung
2052 - 2057
Datum der Veröffentlichung
2014
Status
Published
Herausgeber
Wiley
Herausgeber URL
http://dx.doi.org/10.1002/asia.201402271
Datum der Datenerfassung
2023
Titel
The Synthesis of Dendritic EDOT–Peptide Conjugates and their Multistimuli‐Responsive Self‐Assembly into Supramolecular Nanorods and Fibers in Water
Ausgabe der Zeitschrift
9

Datenquelle: Crossref

Abstract
We report the synthesis of amphiphilic dendritic EDOT-peptide conjugates and discuss their stimuli-responsive self-assembly into polyanionic nanorods in water. In order to expand the general concept of frustrated growth, whereby attractive supramolecular interactions within the enlarged π-system of the hydrophobic core of a dendritic peptide are hampered by repulsive interactions in the hydrophilic periphery, we show that changes in the pH and ionic strength are both able to independently trigger the self-assembly of the dendritic monomers into supramolecular nanorods and nanofibers. These transitions are analyzed using circular dichroism and fluorescence spectroscopic methods, and the resulting supramolecular polymers are characterized by transmission electron microscopy.
Addresses
  • Organic Chemistry Institute and CeNTech, Westfälische Wilhelms-Universität Münster, Corrensstrasse 40, 48149 Münster (Germany).
Autoren
  • Patrick Ahlers
  • Hendrik Frisch
  • Daniel Spitzer
  • Zuzana Vobecka
  • Filipe Vilela
  • Pol Besenius
DOI
10.1002/asia.201402271
eISSN
1861-471X
Externe Identifier
  • PubMed Identifier: 24839177
Open access
false
ISSN
1861-4728
Ausgabe der Veröffentlichung
8
Zeitschrift
Chemistry, an Asian journal
Sprache
eng
Medium
Print-Electronic
Online publication date
2014
Paginierung
2052 - 2057
Datum der Veröffentlichung
2014
Status
Published
Datum der Datenerfassung
2014
Titel
The synthesis of dendritic EDOT-peptide conjugates and their multistimuli-responsive self-assembly into supramolecular nanorods and fibers in water.
Sub types
  • Journal Article
Ausgabe der Zeitschrift
9

Datenquelle: Europe PubMed Central

Abstract
We report the synthesis of amphiphilic dendritic EDOT-peptide conjugates and discuss their stimuli-responsive self-assembly into polyanionic nanorods in water. In order to expand the general concept of frustrated growth, whereby attractive supramolecular interactions within the enlarged π-system of the hydrophobic core of a dendritic peptide are hampered by repulsive interactions in the hydrophilic periphery, we show that changes in the pH and ionic strength are both able to independently trigger the self-assembly of the dendritic monomers into supramolecular nanorods and nanofibers. These transitions are analyzed using circular dichroism and fluorescence spectroscopic methods, and the resulting supramolecular polymers are characterized by transmission electron microscopy.
Autoren
  • Patrick Ahlers
  • Hendrik Frisch
  • Daniel Spitzer
  • Zuzana Vobecka
  • Filipe Vilela
  • Pol Besenius
Autoren-URL
https://www.ncbi.nlm.nih.gov/pubmed/24839177
DOI
10.1002/asia.201402271
eISSN
1861-471X
Ausgabe der Veröffentlichung
8
Zeitschrift
Chem Asian J
Schlüsselwörter
  • nanostructures
  • pH switch
  • self-assembly
  • stimuli-responsive
  • supramolecular polymer
Sprache
eng
Country
Germany
Paginierung
2052 - 2057
Datum der Veröffentlichung
2014
Status
Published
Datum, an dem der Datensatz öffentlich gemacht wurde
2015
Titel
The synthesis of dendritic EDOT-peptide conjugates and their multistimuli-responsive self-assembly into supramolecular nanorods and fibers in water.
Sub types
  • Journal Article
Ausgabe der Zeitschrift
9

Datenquelle: PubMed

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