Reactivity, syntheses, and crystal structures of Na5[MO2][X] with M = Co+, Ni+, Cu+; X = CO32-, SO42-, SO32-, S2-, and Na25[CuO2]5[SO4]4[S]

Publikationstyp:
Zeitschriftenaufsatz
Metadaten:
Autoren
  • P Amann
  • A Möller
Autoren-URL
https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:000185744500002&DestLinkType=FullRecord&DestApp=WOS_CPL
DOI
10.1002/zaac.200300126
Externe Identifier
  • Clarivate Analytics Document Solution ID: 728YT
ISSN
0044-2313
Ausgabe der Veröffentlichung
10
Zeitschrift
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
Schlüsselwörter
  • crystal structure
  • sodium
  • oxides
  • cobalt
  • nickel
  • copper
  • reactivity
  • IR-spectroscopy
Paginierung
1643 - 1650
Datum der Veröffentlichung
2003
Status
Published
Titel
Reactivity, syntheses, and crystal structures of Na<sub>5</sub>[MO<sub>2</sub>][X] with M = Co<SUP>+</SUP>, Ni<SUP>+</SUP>, Cu<SUP>+</SUP>; X = CO<sub>3</sub><SUP>2-</SUP>, SO<sub>4</sub><SUP>2-</SUP>, SO<sub>3</sub><SUP>2-</SUP>, S<SUP>2-</SUP>, and Na<sub>25</sub>[CuO<sub>2</sub>]<sub>5</sub>[SO<sub>4</sub>]<sub>4</sub>[S]
Sub types
  • Article
Ausgabe der Zeitschrift
629

Datenquelle: Web of Science (Lite)

Andere Metadatenquellen:
Abstract
<jats:title>Abstract</jats:title><jats:p>Na<jats:sub>5</jats:sub>[CuO<jats:sub>2</jats:sub>][CO<jats:sub>3</jats:sub>], Na<jats:sub>5</jats:sub>[CuO<jats:sub>2</jats:sub>][SO<jats:sub>3</jats:sub>], Na<jats:sub>5</jats:sub>[CuO<jats:sub>2</jats:sub>][S], and Na<jats:sub>5</jats:sub>[CuO<jats:sub>2</jats:sub>][SO<jats:sub>4</jats:sub>] were obtained as single crystals and powders from reactions of Na<jats:sub>2</jats:sub>O, Cu<jats:sub>2</jats:sub>O, and Na<jats:sub>2</jats:sub>X with X = CO<jats:sub>3</jats:sub><jats:sup>2—</jats:sup>, SO<jats:sub>3</jats:sub><jats:sup>2—</jats:sup>, S<jats:sup>2—</jats:sup>, and SO<jats:sub>4</jats:sub><jats:sup>2—</jats:sup>, respectively. A redox reaction between CdO and Co metal occurs in the presence of Na<jats:sub>2</jats:sub>O and Na<jats:sub>2</jats:sub>X, yielding Na<jats:sub>5</jats:sub>[CoO<jats:sub>2</jats:sub>][X] with X = CO<jats:sub>3</jats:sub><jats:sup>2—</jats:sup> and S<jats:sup>2—</jats:sup>. From a mixture of Na<jats:sub>2</jats:sub>SO<jats:sub>4</jats:sub>, CdO and Na<jats:sub>2</jats:sub>O in Ni‐containers we observed the formation of Na<jats:sub>5</jats:sub>[NiO<jats:sub>2</jats:sub>][S] single crystals. Single crystals of Na<jats:sub>25</jats:sub>[CuO<jats:sub>2</jats:sub>]<jats:sub>5</jats:sub>[SO<jats:sub>4</jats:sub>]<jats:sub>4</jats:sub>[S] can be grown by annealing Na<jats:sub>5</jats:sub>[CuO<jats:sub>2</jats:sub>][SO<jats:sub>3</jats:sub>] at 600 °C, leading to the decomposition of SO<jats:sub>3</jats:sub><jats:sup>2—</jats:sup>, yielding SO<jats:sub>4</jats:sub><jats:sup>2—</jats:sup> and S<jats:sup>2—</jats:sup> at 550 °C. The structures have been determined from single crystal data and powder data. All structures contain the isolated complex [MO<jats:sub>2</jats:sub>]<jats:sup>3—</jats:sup> in a dumb‐bell like arrangement. The main feature of these compounds is that the anions SO<jats:sub>4</jats:sub><jats:sup>2—</jats:sup>, SO<jats:sub>3</jats:sub><jats:sup>2—</jats:sup>, CO<jats:sub>3</jats:sub><jats:sup>2—</jats:sup> and S<jats:sup>2—</jats:sup> are not connected to the transition metal. The formation of Na<jats:sub>5</jats:sub>[CuO<jats:sub>2</jats:sub>][X] (X = S<jats:sup>2—</jats:sup>, SO<jats:sub>4</jats:sub><jats:sup>2—</jats:sup>, SO<jats:sub>3</jats:sub><jats:sup>2—</jats:sup>, CO<jats:sub>3</jats:sub><jats:sup>2—</jats:sup>) has been studied by thermal analysis and <jats:italic>in situ</jats:italic> X‐ray diffraction techniques. Infrared spectra confirm the presence of SO<jats:sub>4</jats:sub><jats:sup>2—</jats:sup>, SO<jats:sub>3</jats:sub><jats:sup>2—</jats:sup>, and CO<jats:sub>3</jats:sub><jats:sup>2—</jats:sup>, respectively, in the structures.</jats:p>
Autoren
  • Peter Amann
  • Angela Möller
DOI
10.1002/zaac.200300126
eISSN
1521-3749
ISSN
0044-2313
Ausgabe der Veröffentlichung
10
Zeitschrift
Zeitschrift für anorganische und allgemeine Chemie
Sprache
en
Online publication date
2003
Paginierung
1643 - 1650
Datum der Veröffentlichung
2003
Status
Published
Herausgeber
Wiley
Herausgeber URL
http://dx.doi.org/10.1002/zaac.200300126
Datum der Datenerfassung
2023
Titel
Reactivity, Syntheses, and Crystal Structures of Na<sub>5</sub>[MO<sub>2</sub>][X] with M = Co<sup>+</sup>, Ni<sup>+</sup>, Cu<sup>+</sup>; X = CO<sub>3</sub><sup>2—</sup>, SO<sub>4</sub><sup>2—</sup>, SO<sub>3</sub><sup>2—</sup>, S<sup>2—</sup>, and Na<sub>25</sub>[CuO<sub>2</sub>]<sub>5</sub>[SO<sub>4</sub>]<sub>4</sub>[S]
Ausgabe der Zeitschrift
629

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