Application of a Mild Hydrothermal Approach Containing an in Situ Reduction Step to the Growth of Single Crystals of the Quaternary U(IV)-Containing Fluorides Na4MU6F30 (M = Mn2+, Co2+, Ni2+, Cu2+, and Zn2+) Crystal Growth, Structures, and Magnetic Properties
- Publikationstyp:
- Zeitschriftenaufsatz
- Metadaten:
-
- Autoren
- Jeongho Yeon
- Mark D Smith
- Joshua Tapp
- Angela Moeller
- Hans-Conrad zur Loye
- Autoren-URL
- https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:000332922600040&DestLinkType=FullRecord&DestApp=WOS_CPL
- DOI
- 10.1021/ja412725r
- Externe Identifier
- Clarivate Analytics Document Solution ID: AD0KJ
- PubMed Identifier: 24593283
- ISSN
- 0002-7863
- Ausgabe der Veröffentlichung
- 10
- Zeitschrift
- JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Paginierung
- 3955 - 3963
- Datum der Veröffentlichung
- 2014
- Status
- Published
- Titel
- Application of a Mild Hydrothermal Approach Containing an in Situ Reduction Step to the Growth of Single Crystals of the Quaternary U(IV)-Containing Fluorides Na<sub>4</sub>MU<sub>6</sub>F<sub>30</sub> (M = Mn<SUP>2+</SUP>, Co<SUP>2+</SUP>, Ni<SUP>2+</SUP>, Cu<SUP>2+</SUP>, and Zn<SUP>2+</SUP>) Crystal Growth, Structures, and Magnetic Properties
- Sub types
- Article
- Ausgabe der Zeitschrift
- 136
Datenquelle: Web of Science (Lite)
- Andere Metadatenquellen:
-
- Autoren
- Jeongho Yeon
- Mark D Smith
- Joshua Tapp
- Angela Möller
- Hans-Conrad zur Loye
- DOI
- 10.1021/ja412725r
- eISSN
- 1520-5126
- ISSN
- 0002-7863
- Ausgabe der Veröffentlichung
- 10
- Zeitschrift
- Journal of the American Chemical Society
- Sprache
- en
- Online publication date
- 2014
- Paginierung
- 3955 - 3963
- Datum der Veröffentlichung
- 2014
- Status
- Published
- Herausgeber
- American Chemical Society (ACS)
- Herausgeber URL
- http://dx.doi.org/10.1021/ja412725r
- Datum der Datenerfassung
- 2023
- Titel
- Application of a Mild Hydrothermal Approach Containing an in Situ Reduction Step to the Growth of Single Crystals of the Quaternary U(IV)-Containing Fluorides Na<sub>4</sub>MU<sub>6</sub>F<sub>30</sub> (M = Mn<sup>2+</sup>, Co<sup>2+</sup>, Ni<sup>2+</sup>, Cu<sup>2+</sup>, and Zn<sup>2+</sup>) Crystal Growth, Structures, and Magnetic Properties
- Ausgabe der Zeitschrift
- 136
Datenquelle: Crossref
- Abstract
- A family of rare U(IV)-containing quaternary fluorides, Na4MU6F30 (M = Mn(2+), Co(2+), Ni(2+), Cu(2+), and Zn(2+)), was synthesized in single crystal form via a mild hydrothermal technique utilizing an in situ U(VI) to U(IV) reduction step. The modified hydrothermal route is described, and the conditions to obtain single crystals in high yield are detailed. The crystal structures were determined by single crystal X-ray diffraction. The isostructural fluorides crystallize in a new structure type in the trigonal space group P3̅c1. They exhibit a complex three-dimensional crystal structure consisting of corner- and edge-shared UF9 and MF6 polyhedra. The main building block, a U6F30(6-) group, is arranged to create two distinct hexagonal channels, inside which MF6 octahedra and Na(+) cations are located. The copper-containing member of the series, Na4CuU6F30, is unusual in that the Cu(2+) cation exhibits a rare symmetrical coordination environment consisting of six identical Cu-F bond distances, indicating the lack of the expected Jahn-Teller distortion. Magnetic susceptibility measurements of Na4ZnU6F30 yielded an effective magnetic moment of 3.42 μB for the U(4+) (f(2)) cation in the structure. Measurements of the other members containing magnetic transition-metal cations in addition to U(4+), Na4MU6F30 (M = Mn(2+), Co(2+), Ni(2+), and Cu(2+)) yielded total effective magnetic moments of 10.2, 9.84, 8.87, and 8.52 μB for the Mn-, Co-, Ni-, and Cu-containing materials, respectively. No evidence for long-range magnetic ordering was found down to 2 K. Measurements of the magnetization as a function of applied magnetic field at 2 K for Na4MnU6F30 confirmed that the U(4+) magnetic cation exhibits a nonmagnetic singlet ground state at low temperature. Thermal stability measurements and UV-vis diffuse reflectance spectroscopy are also reported.
- Addresses
- Department of Chemistry and Biochemistry, University of South Carolina , Columbia, South Carolina 29208, United States.
- Autoren
- Jeongho Yeon
- Mark D Smith
- Joshua Tapp
- Angela Möller
- Hans-Conrad zur Loye
- DOI
- 10.1021/ja412725r
- eISSN
- 1520-5126
- Externe Identifier
- PubMed Identifier: 24593283
- Funding acknowledgements
- National Science Foundation: DMR-1149899
- Office of Basic Energy Sciences: DE-SC0008664
- Open access
- false
- ISSN
- 0002-7863
- Ausgabe der Veröffentlichung
- 10
- Zeitschrift
- Journal of the American Chemical Society
- Sprache
- eng
- Medium
- Print-Electronic
- Online publication date
- 2014
- Paginierung
- 3955 - 3963
- Datum der Veröffentlichung
- 2014
- Status
- Published
- Datum der Datenerfassung
- 2014
- Titel
- Application of a mild hydrothermal approach containing an in situ reduction step to the growth of single crystals of the quaternary U(IV)-containing fluorides Na4MU6F30 (M = Mn2+, Co2+, Ni2+, Cu2+, and Zn2+) crystal growth, structures, and magnetic properties.
- Sub types
- Journal Article
- Ausgabe der Zeitschrift
- 136
Datenquelle: Europe PubMed Central
- Abstract
- A family of rare U(IV)-containing quaternary fluorides, Na4MU6F30 (M = Mn(2+), Co(2+), Ni(2+), Cu(2+), and Zn(2+)), was synthesized in single crystal form via a mild hydrothermal technique utilizing an in situ U(VI) to U(IV) reduction step. The modified hydrothermal route is described, and the conditions to obtain single crystals in high yield are detailed. The crystal structures were determined by single crystal X-ray diffraction. The isostructural fluorides crystallize in a new structure type in the trigonal space group P3̅c1. They exhibit a complex three-dimensional crystal structure consisting of corner- and edge-shared UF9 and MF6 polyhedra. The main building block, a U6F30(6-) group, is arranged to create two distinct hexagonal channels, inside which MF6 octahedra and Na(+) cations are located. The copper-containing member of the series, Na4CuU6F30, is unusual in that the Cu(2+) cation exhibits a rare symmetrical coordination environment consisting of six identical Cu-F bond distances, indicating the lack of the expected Jahn-Teller distortion. Magnetic susceptibility measurements of Na4ZnU6F30 yielded an effective magnetic moment of 3.42 μB for the U(4+) (f(2)) cation in the structure. Measurements of the other members containing magnetic transition-metal cations in addition to U(4+), Na4MU6F30 (M = Mn(2+), Co(2+), Ni(2+), and Cu(2+)) yielded total effective magnetic moments of 10.2, 9.84, 8.87, and 8.52 μB for the Mn-, Co-, Ni-, and Cu-containing materials, respectively. No evidence for long-range magnetic ordering was found down to 2 K. Measurements of the magnetization as a function of applied magnetic field at 2 K for Na4MnU6F30 confirmed that the U(4+) magnetic cation exhibits a nonmagnetic singlet ground state at low temperature. Thermal stability measurements and UV-vis diffuse reflectance spectroscopy are also reported.
- Autoren
- Jeongho Yeon
- Mark D Smith
- Joshua Tapp
- Angela Möller
- Hans-Conrad zur Loye
- Autoren-URL
- https://www.ncbi.nlm.nih.gov/pubmed/24593283
- DOI
- 10.1021/ja412725r
- eISSN
- 1520-5126
- Ausgabe der Veröffentlichung
- 10
- Zeitschrift
- J Am Chem Soc
- Sprache
- eng
- Country
- United States
- Paginierung
- 3955 - 3963
- Datum der Veröffentlichung
- 2014
- Status
- Published
- Datum, an dem der Datensatz öffentlich gemacht wurde
- 2015
- Titel
- Application of a mild hydrothermal approach containing an in situ reduction step to the growth of single crystals of the quaternary U(IV)-containing fluorides Na4MU6F30 (M = Mn2+, Co2+, Ni2+, Cu2+, and Zn2+) crystal growth, structures, and magnetic properties.
- Sub types
- Journal Article
- Ausgabe der Zeitschrift
- 136
Datenquelle: PubMed
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