Control of Exchange Interactions in Trinuclear Complexes Based on Orthogonal Magnetic Orbitals

Publikationstyp:
Zeitschriftenaufsatz
Metadaten:
Autoren
  • Birgit Weber
  • Jaroslava Obel
  • Lucia R Lorenz
  • Wolfgang Bauer
  • Luca Carrella
  • Eva Rentschler
Autoren-URL
https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:000273378100009&DestLinkType=FullRecord&DestApp=WOS_CPL
DOI
10.1002/ejic.200900847
eISSN
1099-0682
Externe Identifier
  • Clarivate Analytics Document Solution ID: 540YU
ISSN
1434-1948
Ausgabe der Veröffentlichung
36
Zeitschrift
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Schlüsselwörter
  • Magnetic properties
  • Schiff bases
  • Copper
  • Vanadium
  • N,O ligands
Paginierung
5535 - 5540
Datum der Veröffentlichung
2009
Status
Published
Titel
Control of Exchange Interactions in Trinuclear Complexes Based on Orthogonal Magnetic Orbitals
Sub types
  • Article

Datenquelle: Web of Science (Lite)

Andere Metadatenquellen:
Abstract
<jats:title>Abstract</jats:title><jats:p>The reaction of copper(II) acetate with the tetradentate Schiff base like ligand H<jats:sub>4</jats:sub>L {(<jats:italic>E</jats:italic>,<jats:italic>E</jats:italic>)‐[{diethyl 2,2′‐[4,5‐dihydroxy‐1,2‐phenylenebis(iminomethylidyne)]bis(3‐oxobutanoate)}] leads to the formation of the square planar N<jats:sub>2</jats:sub>O<jats:sub>2</jats:sub> coordinated complex [H<jats:sub>2</jats:sub>CuL]. Reaction of two equivalents of this complex with copper(II) acetylacetonato or vanadyl(IV) acetylacetonato yields the trinuclear complexes [V(O)Cu<jats:sub>2</jats:sub>L<jats:sub>2</jats:sub>][N(<jats:italic>n</jats:italic>Bu)<jats:sub>4</jats:sub>]<jats:sub>2</jats:sub><jats:bold>·</jats:bold>2MeOH (<jats:bold>1</jats:bold>) and [Cu<jats:sub>3</jats:sub>L<jats:sub>2</jats:sub>][N(<jats:italic>n</jats:italic>Bu)<jats:sub>4</jats:sub>]<jats:sub>2</jats:sub><jats:bold>·</jats:bold>2DMF (<jats:bold>2</jats:bold>). Both complexes were characterised by using magnetic measurements and X‐ray crystallography. Special attention was given to the spin‐exchange coupling through the bridging phenylene ring. The principle of strict orthogonality of the magnetic orbitals can be applied to explain the results of the susceptibility measurements. (© Wiley‐VCH Verlag GmbH &amp; Co. KGaA, 69451 Weinheim, Germany, 2009)</jats:p>
Autoren
  • Birgit Weber
  • Jaroslava Obel
  • Lucia R Lorenz
  • Wolfgang Bauer
  • Luca Carrella
  • Eva Rentschler
DOI
10.1002/ejic.200900847
eISSN
1099-0682
ISSN
1434-1948
Ausgabe der Veröffentlichung
36
Zeitschrift
European Journal of Inorganic Chemistry
Sprache
en
Online publication date
2009
Paginierung
5535 - 5540
Datum der Veröffentlichung
2009
Status
Published
Herausgeber
Wiley
Herausgeber URL
http://dx.doi.org/10.1002/ejic.200900847
Datum der Datenerfassung
2023
Titel
Control of Exchange Interactions in Trinuclear Complexes Based on Orthogonal Magnetic Orbitals
Ausgabe der Zeitschrift
2009

Datenquelle: Crossref

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