The First 1,3,4-Oxadiazole Based Dinuclear Iron(II) Complexes Showing Spin Crossover Behavior with Hysteresis
- Publikationstyp:
- Zeitschriftenaufsatz
- Metadaten:
-
- Autoren
- Christian Koehler
- Eva Rentschler
- Autoren-URL
- https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:000376005600009&DestLinkType=FullRecord&DestApp=WOS_CPL
- DOI
- 10.1002/ejic.201501278
- eISSN
- 1099-0682
- Externe Identifier
- Clarivate Analytics Document Solution ID: DM0AU
- ISSN
- 1434-1948
- Ausgabe der Veröffentlichung
- 13-14
- Zeitschrift
- EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
- Schlüsselwörter
- Spin crossover
- Magnetic properties
- 1
- 3
- 4-Oxadiazole
- Hysteresis
- Iron
- Paginierung
- 1955 - 1960
- Datum der Veröffentlichung
- 2016
- Status
- Published
- Titel
- The First 1,3,4-Oxadiazole Based Dinuclear Iron(II) Complexes Showing Spin Crossover Behavior with Hysteresis
- Sub types
- Article
Datenquelle: Web of Science (Lite)
- Andere Metadatenquellen:
-
- Abstract
- <jats:title>Abstract</jats:title><jats:p>Three new dinuclear complexes [Fe<jats:sup>II</jats:sup><jats:sub>2</jats:sub>(μ‐<jats:bold>L</jats:bold>)<jats:sub>2</jats:sub>]X<jats:sub>4</jats:sub> (<jats:bold>L</jats:bold> is the bis‐tridentate ligand 2,5‐bis{[(2‐pyridylmethyl)amino]methyl}‐1,3,4‐oxadiazole and X = ClO<jats:sub>4</jats:sub><jats:sup>–</jats:sup>, BF<jats:sub>4</jats:sub><jats:sup>–</jats:sup> and CF<jats:sub>3</jats:sub>SO<jats:sub>3</jats:sub><jats:sup>–</jats:sup>) have been synthesized and fully characterized by single‐crystal X‐ray diffraction, Mössbauer spectroscopy and magnetic susceptibility measurements. Upon cooling, a trapped [high‐spin–low‐spin] state of the iron(II) centres is detected. Depending on the counterion, a pronounced thermal hysteresis is found. In one case, it was possible to observe a space group change that accompanies the spin transition. This is the first system showing spin crossover based on an oxadiazole ligand.</jats:p>
- Autoren
- Christian Köhler
- Eva Rentschler
- DOI
- 10.1002/ejic.201501278
- eISSN
- 1099-0682
- ISSN
- 1434-1948
- Ausgabe der Veröffentlichung
- 13-14
- Zeitschrift
- European Journal of Inorganic Chemistry
- Sprache
- en
- Online publication date
- 2015
- Paginierung
- 1955 - 1960
- Datum der Veröffentlichung
- 2016
- Status
- Published
- Herausgeber
- Wiley
- Herausgeber URL
- http://dx.doi.org/10.1002/ejic.201501278
- Datum der Datenerfassung
- 2023
- Titel
- The First 1,3,4‐Oxadiazole Based Dinuclear Iron(II) Complexes Showing Spin Crossover Behavior with Hysteresis
- Ausgabe der Zeitschrift
- 2016
Datenquelle: Crossref
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