Dual Application of (Aqua)(Chlorido)(Porphyrinato)Chromium(III) as Hypersensitive Amine-Triggered ON Switch and for Dioxygen Activation
- Publikationstyp:
- Zeitschriftenaufsatz
- Metadaten:
-
- Autoren
- Philip Heier
- Nicolas D Boscher
- Patrick Choquet
- Katja Heinze
- Autoren-URL
- https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:000343527700039&DestLinkType=FullRecord&DestApp=WOS_CPL
- DOI
- 10.1021/ic501644z
- eISSN
- 1520-510X
- Externe Identifier
- Clarivate Analytics Document Solution ID: AR3ZL
- PubMed Identifier: 25271996
- ISSN
- 0020-1669
- Ausgabe der Veröffentlichung
- 20
- Zeitschrift
- INORGANIC CHEMISTRY
- Paginierung
- 11086 - 11095
- Datum der Veröffentlichung
- 2014
- Status
- Published
- Titel
- Dual Application of (Aqua)(Chlorido)(Porphyrinato)Chromium(III) as Hypersensitive Amine-Triggered ON Switch and for Dioxygen Activation
- Sub types
- Article
- Ausgabe der Zeitschrift
- 53
Datenquelle: Web of Science (Lite)
- Andere Metadatenquellen:
-
- Autoren
- Philip Heier
- Nicolas D Boscher
- Patrick Choquet
- Katja Heinze
- DOI
- 10.1021/ic501644z
- eISSN
- 1520-510X
- ISSN
- 0020-1669
- Ausgabe der Veröffentlichung
- 20
- Zeitschrift
- Inorganic Chemistry
- Sprache
- en
- Online publication date
- 2014
- Paginierung
- 11086 - 11095
- Datum der Veröffentlichung
- 2014
- Status
- Published
- Herausgeber
- American Chemical Society (ACS)
- Herausgeber URL
- http://dx.doi.org/10.1021/ic501644z
- Datum der Datenerfassung
- 2023
- Titel
- Dual Application of (Aqua)(Chlorido)(Porphyrinato)Chromium(III) as Hypersensitive Amine-Triggered ON Switch and for Dioxygen Activation
- Ausgabe der Zeitschrift
- 53
Datenquelle: Crossref
- Abstract
- Although synthesis and substitution reactions of chlorido chromium(III) porphyrins Cr(III)(TPP)(Cl)(L) (H2TPP = 5,10,15,20-tetraphenyl porphyrin, L = pyridine, H2O, ROH, etc.), have been well-established in coordination chemistry for decades, an unexpected dichotomous reactivity of Cr(III)(TPP)(Cl)(H2O) (1) toward amines is disclosed here. This reactivity leads to the application of 1 as highly sensitive substoichiometric and irreversible ON switch for amine detection by an autocatalytic pathway. The concomitant activation of O2 by the 1/amine system is furthermore exploited in an electrochemically driven epoxidation of norbonene using O2 as initial oxidant.
- Addresses
- Institute of Inorganic and Analytical Chemistry, Johannes Gutenberg University of Mainz , D-55128 Mainz, Germany.
- Autoren
- Philip Heier
- Nicolas D Boscher
- Patrick Choquet
- Katja Heinze
- DOI
- 10.1021/ic501644z
- eISSN
- 1520-510X
- Externe Identifier
- PubMed Identifier: 25271996
- Funding acknowledgements
- Fonds National de la Recherche Luxembourg: Surfamine
- Open access
- false
- ISSN
- 0020-1669
- Ausgabe der Veröffentlichung
- 20
- Zeitschrift
- Inorganic chemistry
- Sprache
- eng
- Medium
- Print-Electronic
- Online publication date
- 2014
- Paginierung
- 11086 - 11095
- Datum der Veröffentlichung
- 2014
- Status
- Published
- Datum der Datenerfassung
- 2014
- Titel
- Dual application of (aqua)(chlorido)(porphyrinato)chromium(III) as hypersensitive amine-triggered ON switch and for dioxygen activation.
- Sub types
- Journal Article
- Ausgabe der Zeitschrift
- 53
Datenquelle: Europe PubMed Central
- Abstract
- Although synthesis and substitution reactions of chlorido chromium(III) porphyrins Cr(III)(TPP)(Cl)(L) (H2TPP = 5,10,15,20-tetraphenyl porphyrin, L = pyridine, H2O, ROH, etc.), have been well-established in coordination chemistry for decades, an unexpected dichotomous reactivity of Cr(III)(TPP)(Cl)(H2O) (1) toward amines is disclosed here. This reactivity leads to the application of 1 as highly sensitive substoichiometric and irreversible ON switch for amine detection by an autocatalytic pathway. The concomitant activation of O2 by the 1/amine system is furthermore exploited in an electrochemically driven epoxidation of norbonene using O2 as initial oxidant.
- Autoren
- Philip Heier
- Nicolas D Boscher
- Patrick Choquet
- Katja Heinze
- Autoren-URL
- https://www.ncbi.nlm.nih.gov/pubmed/25271996
- DOI
- 10.1021/ic501644z
- eISSN
- 1520-510X
- Ausgabe der Veröffentlichung
- 20
- Zeitschrift
- Inorg Chem
- Sprache
- eng
- Country
- United States
- Paginierung
- 11086 - 11095
- Datum der Veröffentlichung
- 2014
- Status
- Published
- Datum, an dem der Datensatz öffentlich gemacht wurde
- 2015
- Titel
- Dual application of (aqua)(chlorido)(porphyrinato)chromium(III) as hypersensitive amine-triggered ON switch and for dioxygen activation.
- Sub types
- Journal Article
- Ausgabe der Zeitschrift
- 53
Datenquelle: PubMed
- Beziehungen:
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