Chemical Reaction Monitoring using Zero-Field Nuclear Magnetic Resonance Enables Study of Heterogeneous Samples in Metal Containers
- Publikationstyp:
- Zeitschriftenaufsatz
- Metadaten:
-
- Autoren
- Dudari B Burueva
- James Eills
- John W Blanchard
- Antoine Garcon
- Roman Picazo-Frutos
- Kirill V Kovtunov
- Igor V Koptyug
- Dmitry Budker
- Autoren-URL
- https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:000563902300001&DestLinkType=FullRecord&DestApp=WOS_CPL
- DOI
- 10.1002/anie.202006266
- eISSN
- 1521-3773
- Externe Identifier
- Clarivate Analytics Document Solution ID: NO1DR
- PubMed Identifier: 32510813
- ISSN
- 1433-7851
- Ausgabe der Veröffentlichung
- 39
- Zeitschrift
- ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Schlüsselwörter
- catalysis
- hyperpolarization
- NMR spectroscopy
- reaction monitoring
- zero-field
- Paginierung
- 17026 - 17032
- Datum der Veröffentlichung
- 2020
- Status
- Published
- Titel
- Chemical Reaction Monitoring using Zero-Field Nuclear Magnetic Resonance Enables Study of Heterogeneous Samples in Metal Containers
- Sub types
- Article
- Ausgabe der Zeitschrift
- 59
Datenquelle: Web of Science (Lite)
- Andere Metadatenquellen:
-
- Abstract
- <jats:title>Abstract</jats:title><jats:p>We demonstrate that heterogeneous/biphasic chemical reactions can be monitored with high spectroscopic resolution using zero‐field nuclear magnetic resonance spectroscopy. This is possible because magnetic susceptibility broadening is negligible at ultralow magnetic fields. We show the two‐step hydrogenation of dimethyl acetylenedicarboxylate with para‐enriched hydrogen gas in conventional glass NMR tubes, as well as in a titanium tube. The low frequency zero‐field NMR signals ensure that there is no significant signal attenuation arising from shielding by the electrically conductive sample container. This method paves the way for in situ monitoring of reactions in complex heterogeneous multiphase systems and in reactors made of conductive materials while maintaining resolution and chemical specificity.</jats:p>
- Autoren
- Dudari B Burueva
- James Eills
- John W Blanchard
- Antoine Garcon
- Román Picazo‐Frutos
- Kirill V Kovtunov
- Igor V Koptyug
- Dmitry Budker
- DOI
- 10.1002/anie.202006266
- eISSN
- 1521-3773
- ISSN
- 1433-7851
- Ausgabe der Veröffentlichung
- 39
- Zeitschrift
- Angewandte Chemie International Edition
- Sprache
- en
- Online publication date
- 2020
- Paginierung
- 17026 - 17032
- Datum der Veröffentlichung
- 2020
- Status
- Published
- Herausgeber
- Wiley
- Herausgeber URL
- http://dx.doi.org/10.1002/anie.202006266
- Datum der Datenerfassung
- 2023
- Titel
- Chemical Reaction Monitoring using Zero‐Field Nuclear Magnetic Resonance Enables Study of Heterogeneous Samples in Metal Containers
- Ausgabe der Zeitschrift
- 59
Datenquelle: Crossref
- Abstract
- We demonstrate that heterogeneous/biphasic chemical reactions can be monitored with high spectroscopic resolution using zero-field nuclear magnetic resonance spectroscopy. This is possible because magnetic susceptibility broadening is negligible at ultralow magnetic fields. We show the two-step hydrogenation of dimethyl acetylenedicarboxylate with para-enriched hydrogen gas in conventional glass NMR tubes, as well as in a titanium tube. The low frequency zero-field NMR signals ensure that there is no significant signal attenuation arising from shielding by the electrically conductive sample container. This method paves the way for in situ monitoring of reactions in complex heterogeneous multiphase systems and in reactors made of conductive materials while maintaining resolution and chemical specificity.
- Addresses
- Laboratory of Magnetic Resonance Microimaging, International Tomography Center, 630090, Novosibirsk, Russia.
- Autoren
- Dudari B Burueva
- James Eills
- John W Blanchard
- Antoine Garcon
- Román Picazo-Frutos
- Kirill V Kovtunov
- Igor V Koptyug
- Dmitry Budker
- DOI
- 10.1002/anie.202006266
- eISSN
- 1521-3773
- Externe Identifier
- PubMed Identifier: 32510813
- PubMed Central ID: PMC7540358
- Funding acknowledgements
- National Science Foundation: CHE-1709944
- Russian Foundation for Basic Research: 19-29-10003
- European Research Council: 695405
- Russian Foundation for Basic Research (RFBR): 19-29-10003
- H2020 Marie Skłodowska-Curie Actions: 766402
- Ministry of Education and Science of the Russian Federation: AAAA-A16-116121510087-5
- Open access
- true
- ISSN
- 1433-7851
- Ausgabe der Veröffentlichung
- 39
- Zeitschrift
- Angewandte Chemie (International ed. in English)
- Sprache
- eng
- Medium
- Print-Electronic
- Online publication date
- 2020
- Open access status
- Open Access
- Paginierung
- 17026 - 17032
- Datum der Veröffentlichung
- 2020
- Status
- Published
- Publisher licence
- CC BY-NC
- Datum der Datenerfassung
- 2020
- Titel
- Chemical Reaction Monitoring using Zero-Field Nuclear Magnetic Resonance Enables Study of Heterogeneous Samples in Metal Containers.
- Sub types
- research-article
- Journal Article
- Ausgabe der Zeitschrift
- 59
Files
https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/anie.202006266 https://europepmc.org/articles/PMC7540358?pdf=render
Datenquelle: Europe PubMed Central
- Abstract
- We demonstrate that heterogeneous/biphasic chemical reactions can be monitored with high spectroscopic resolution using zero-field nuclear magnetic resonance spectroscopy. This is possible because magnetic susceptibility broadening is negligible at ultralow magnetic fields. We show the two-step hydrogenation of dimethyl acetylenedicarboxylate with para-enriched hydrogen gas in conventional glass NMR tubes, as well as in a titanium tube. The low frequency zero-field NMR signals ensure that there is no significant signal attenuation arising from shielding by the electrically conductive sample container. This method paves the way for in situ monitoring of reactions in complex heterogeneous multiphase systems and in reactors made of conductive materials while maintaining resolution and chemical specificity.
- Autoren
- Dudari B Burueva
- James Eills
- John W Blanchard
- Antoine Garcon
- Román Picazo-Frutos
- Kirill V Kovtunov
- Igor V Koptyug
- Dmitry Budker
- Autoren-URL
- https://www.ncbi.nlm.nih.gov/pubmed/32510813
- DOI
- 10.1002/anie.202006266
- eISSN
- 1521-3773
- Externe Identifier
- PubMed Central ID: PMC7540358
- Funding acknowledgements
- H2020 Marie Skłodowska-Curie Actions: 766402
- National Science Foundation: CHE-1709944
- Russian Foundation for Basic Research (RFBR): 19-29-10003
- Ministry of Education and Science of the Russian Federation: AAAA-A16-116121510087-5
- European Research Council: 695405
- Ausgabe der Veröffentlichung
- 39
- Zeitschrift
- Angew Chem Int Ed Engl
- Schlüsselwörter
- NMR spectroscopy
- catalysis
- hyperpolarization
- reaction monitoring
- zero-field
- Sprache
- eng
- Country
- Germany
- Paginierung
- 17026 - 17032
- Datum der Veröffentlichung
- 2020
- Status
- Published
- Titel
- Chemical Reaction Monitoring using Zero-Field Nuclear Magnetic Resonance Enables Study of Heterogeneous Samples in Metal Containers.
- Sub types
- Journal Article
- Ausgabe der Zeitschrift
- 59
Datenquelle: PubMed
- Author's licence
- CC-BY-NC
- Autoren
- Dudari B Burueva
- James Eills
- John W Blanchard
- Antoine Garcon
- Román Picazo-Frutos
- Kirill V Kovtunov
- Igor V Koptyug
- Dmitry Budker
- Hosting institution
- Universitätsbibliothek Mainz
- Sammlungen
- JGU-Publikationen
- Resource version
- Published version
- DOI
- 10.1002/anie.202006266
- File(s) embargoed
- false
- Open access
- true
- ISSN
- 1521-3773
- Ausgabe der Veröffentlichung
- 39
- Zeitschrift
- Angewandte Chemie
- Schlüsselwörter
- 530 Physik
- 530 Physics
- 540 Chemie
- 540 Chemistry and allied sciences
- Sprache
- eng
- Open access status
- Open Access
- Paginierung
- 17026 - 17032
- Datum der Veröffentlichung
- 2020
- Public URL
- https://openscience.ub.uni-mainz.de/handle/20.500.12030/6241
- Herausgeber
- Wiley-VCH
- Herausgeber URL
- https://doi.org/10.1002/anie.202006266
- Datum der Datenerfassung
- 2021
- Datum, an dem der Datensatz öffentlich gemacht wurde
- 2021
- Zugang
- Public
- Titel
- Chemical reaction monitoring using zero-field nuclear magnetic resonance enables study of heterogeneous samples in metal containers
- Ausgabe der Zeitschrift
- 59
Files
burueva_dudari_b.-chemical_react-20210802211757619.pdf
Datenquelle: OPENSCIENCE.UB
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